材料科学
钙钛矿(结构)
卤化物
单晶
化学物理
甲脒
带隙
碘化物
光伏
激发态
Crystal(编程语言)
光电子学
结晶学
无机化学
光伏系统
原子物理学
化学
生态学
物理
计算机科学
程序设计语言
生物
作者
Bo Wu,Nguyễn Huy Tiệp,Zhiliang Ku,Guifang Han,David Giovanni,Nripan Mathews,Hong Jin Fan,Tze Chien Sum
标识
DOI:10.1002/aenm.201600551
摘要
Organic–inorganic halide perovskite single crystals possess many outstanding properties conducive for photovoltaic and optoelectronic applications. However, a clear photophysics picture is still elusive, particularly, their surface and bulk photophysics are inexorably convoluted by the spectral absorbance, defects, coexisting photoexcited species, etc. In this work, an all-optical study is presented that clearly distinguishes the surface kinetics from those of the bulk in the representative methylammonium-lead bromide (MAPbBr3) and -lead iodide (MAPbI3) single crystals. It is found that the bulk recombination lifetime of the MAPbBr3 single crystal is shortened significantly by approximately one to two orders (i.e., from ≈34 to ≈1 ns) at the surface with a surface recombination velocity of around 6.7 × 103 cm s−1. The surface trap density is estimated to be around 6.0 × 1017 cm−3, which is two orders larger than that of the bulk (5.8 × 1015 cm−3). Correspondingly, the diffusion length of the surface excited species is ≈130–160 nm, which is considerably reduced compared to the bulk value of ≈2.6–4.3 μm. Furthermore, the surface region has a wider bandgap that possibly arises from the strong lattice deformation. The findings provide new insights into the intrinsic photophysics essential for single crystal perovskite photovoltaics and optoelectronic devices.
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