化学选择性
化学
二硫代氨基甲酸盐
芳基
选择性
催化作用
组合化学
基础(拓扑)
有机化学
烷基
数学
数学分析
作者
Kang Peng,Hai‐Liang Zhu,Xing Liu,Han‐Ying Peng,Jinquan Chen,Zhi‐Bing Dong
标识
DOI:10.1002/ejoc.201901401
摘要
An efficient C–S/S–S formation for the chemoselective synthesis of aryl dithiocarbamate (C–S formation) and aryl dialkylcarbamo(dithioperoxo)thioate (S–S formation) was studied. The chemoselectivity could be controlled by modulating the reaction temperature, base, and catalyst. The transformation features a simple reaction, easily available starting materials, high selectivity and easy performance, showing its practical synthetic value for the preparation of some potential biologically or pharmaceutically active compounds.
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