吸附
阳离子聚合
化学
朗缪尔吸附模型
甲基蓝
水溶液
可重用性
化学工程
水处理
金属有机骨架
饮用水净化
有机化学
光催化
环境工程
催化作用
软件
计算机科学
工程类
程序设计语言
作者
Wenqing Xiang,Qin Wang,Zhangjian Li,Jiangnan Dong,Haibo Liu,Lin Zhang,Tifeng Xia,Yabing He,Dian Zhao
标识
DOI:10.1016/j.seppur.2023.125268
摘要
The water stability of typical metal–organic frameworks (MOFs) limits the practical applications in water, such as pollutants adsorption. In this work, through the pre-functionalization of hydrophobic methyl groups on the ligand, anionic Bio-MOF-1 was transformed into Bio-MOF-2Me which has excellent water stability, even in acidic and boiling water environments. Bio-MOF-2Me also keeps the negative Zeta potential, enabling it to efficiently adsorbing and separating targeted dyes in mixed aqueous solution of cationic/anionic dyes, with high removal rates of around 99%. According to the Langmuir isotherm model, the maximum adsorption capacity of Bio-MOF-2Me for cationic methyl violet could reach up to 310.2 mg⋅g−1. In order to improve the portability and recyclability of Bio-MOF-2Me-based adsorbents, a mixed matrix membrane (MMM) of Bio-MOF-2Me (Bio-MOF-2Me-MMM) was manufactured. Bio-MOF-2Me-MMM inherits the preferential adsorption and separation properties of Bio-MOF-2Me, which has a maximum adsorption capacity of 157.1 mg⋅g−1 for cationic methyl violet. The adsorption abilities of both Bio-MOF-2Me and Bio-MOF-2Me-MMM own good cyclic reversibility, and the removal efficiency respectively retained 82% (Bio-MOF-2Me) and 72% (Bio-MOF-2Me-MMM) even after five adsorption–desorption cycles. The water stability, good adsorption/separation ability, portability and reusability make ionic Bio-MOF-2Me-MMM a promising candidate for dye wastewater treatment.
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