27.09%-efficiency silicon heterojunction back contact solar cell and going beyond

硅太阳电池 异质结 太阳能电池 材料科学 光电子学 工程物理 纳米技术 物理
作者
Genshun Wang,Qiao Su,Hanbo Tang,Hua Wu,Hao Lin,Can Han,Tingting Wang,Chaowei Xue,Junxiong Lu,Liang Fang,Zhenguo Li,Xixiang Xu,Pingqi Gao
出处
期刊:Nature Communications [Springer Nature]
卷期号:15 (1)
标识
DOI:10.1038/s41467-024-53275-5
摘要

Crystalline-silicon heterojunction back contact solar cells represent the forefront of photovoltaic technology, but encounter significant challenges in managing charge carrier recombination and transport to achieve high efficiency. In this study, we produced highly efficient heterojunction back contact solar cells with a certified efficiency of 27.09% using a laser patterning technique. Our findings indicate that recombination losses primarily arise from the hole-selective contact region and polarity boundaries. We propose solutions to these issues and establish a clear relationship between contact resistivity, series resistance, and the design of the rear-side pattern. Furthermore, we demonstrate that the wafer edge becomes the main channel for current density loss caused by carrier recombination once electrical shading around the electron-selective contact region is mitigated. With the advanced nanocrystalline passivating contact, wafer edge passivation technologies and meticulous optimization of front anti-reflection coating and rear reflector, achieving efficiencies as high as 27.7% is feasible. The management of charge carrier recombination and transport in heterojunction back contact solar cells poses significant challenges in achieving a high efficiency. Here, authors analyze various loss mechanisms of devices fabricated by laser patterning, and achieve a certified efficiency of 27.09%.
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