微型多孔材料
吸附
杂原子
热解
碳纤维
化学工程
氮气
多孔性
材料科学
共轭微孔聚合物
物理吸附
化学
无机化学
有机化学
复合材料
戒指(化学)
复合数
工程类
作者
Duanlian Tang,Xiaoying Lyu,Zhixian Huang,Renwei Xu,Jie Chen,Ting Qiu
标识
DOI:10.1016/j.powtec.2023.118769
摘要
Nitrogen-doped microporous carbon, which features a uniquely tunable porosity, exhibits promisingly high adsorption prospects in the greenhouse gas capture and water treatment. Herein, we propose a series of novel N-doped microporous carbons (CMPAn-C1000), and precisely tune their porosities via a direct pyrolysis of rigid conjugated microporous poly(aniline)s (CMPAn, n = 1, 2, 3) with pore size difference in a molecular level, as achieved by simply tuning their linkers with varying sizes, planarity, and symmetry. The CMPA3-C1000, with a satisfactory amount of nitrogen heteroatoms, high SBET of ∼800 m2 g−1, and large ultra-micropore volume of 0.25 cm3 g−1, has excellent CO2 capture ability (i.e., 5.1 mmol g−1 at 273 K, 1 atm) and Hg(II) adsorption performance (i.e., Qe = 571 mg g−1; k2 = 0.0031 g mg−1 min−1), respectively. CMPA3-C1000 might perform chemisorption towards Hg(II), according to calculations using density functional theory and experimental data; nitrogen atoms in porous carbon contributed to this excellent Hg(II) adsorption.
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