光催化
热液循环
光致发光
异质结
材料科学
碳纤维
纳米复合材料
化学工程
水热合成
原位
纳米技术
水热反应
光化学
催化作用
化学
光电子学
复合数
有机化学
复合材料
工程类
作者
Jing Wang,Minmin Gao,Ghim Wei Ho
出处
期刊:Journal of materials chemistry. A, Materials for energy and sustainability
[The Royal Society of Chemistry]
日期:2014-01-01
卷期号:2 (16): 5703-5703
被引量:122
摘要
In this paper, we demonstrate a series of metal-free and inexpensive TiO2/carbon dot (CD) nanocomposites via facile hydrothermal synthesis from bidentate complexes of a green carbon source, vitamin C (VC). Other than the importance of deriving CDs from alternate carbon materials instead of graphitic precursors, the in situ transformed CDs from VC ensure the formation of chemically coupled heterostructures, TiO2/CDs, which serve as efficient photocatalysts exhibiting a higher H2 evolution rate from photocatalytic reactions up to 9.7 times than that of bare TiO2. Interestingly, the H2 evolution rate can effectively be tuned by VC amounts, hydrothermal temperatures and reaction durations. The mechanism of the enhanced H2 evolution rate was also discussed, in which the synergetic effects of the hydrothermal treatment along with the favourable electron transfer ability and upconverted photoluminescence of CDs contribute to the improved photocatalytic behaviour.
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