烯烃
纳米技术
组合化学
化学
有机合成
有机化学
材料科学
催化作用
作者
Yuqiang Li,Donghai Wu,Hong‐Gang Cheng,Guoyin Yin
标识
DOI:10.1002/anie.201913382
摘要
The direct difunctionalization of alkenes, a cheap and abundant feedstock, represents one of the most attractive strategies for increasing molecular complexity in synthetic organic chemistry. In contrast with the 1,2-difunctionalization of alkenes, recent advances showcase alkene 1,n-difunctionalizations (n≠2) involving metal migration is an emerging and rapidly growing area of research. This promising strategy not only opens a novel avenue for future development of alkene transformations, but also significantly expands upon the bond disconnections available in modern organic synthesis. This Minireview summarizes recent progress in the migratory difunctionalization of alkenes, with an emphasis on the driving force for metal migration.
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