石墨烯
循环伏安法
材料科学
微分脉冲伏安法
分析化学(期刊)
对苯二酚
检出限
X射线光电子能谱
电化学气体传感器
傅里叶变换红外光谱
电极
电化学
化学
化学工程
纳米技术
物理化学
有机化学
色谱法
工程类
作者
Siti Nur Akmar Mohd Yazid,Illyas Md Isa,Noorshida Mohd Ali,Norhayati Hashim,Mohamad Idris Saidin,Mohamad Syahrizal Ahmad,Abdullah M. Asiri,Anish Khan,Rahadian Zainul
标识
DOI:10.1080/03067319.2020.1758079
摘要
A novel electrochemical sensor for sensitive and selective detection of hydroquinone (HQ) was developed using graphene/iridium(III) dimer complex composite modified glassy carbon electrode (graphene/Ir(III) complex/GCE). The composite was characterised by field emission scanning electron microscopy, energy dispersive X-ray microanalysis, Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy. The graphene/Ir(III) complex/GCE has provided higher surface area which was good for catalytic activity and enhanced electrical conductivity that was then examined using differential pulse voltammetry, cyclic voltammetry, and square wave voltammetry. At optimal condition, HQ has been sensitively detected in the ranges of 100–1.5 µM and 1.5–0.05 µM with good sensitivity of 1120.64 μA/mM/cm2 and low detection limit of 1.1 nM (S/N = 3). The graphene/Ir(III) complex/GCE sensor presented the performance advantages of good reproducibility, repeatability, stability and selectivity. The prepared electrode was further applied to detect HQ in real-life water samples, which exhibit the acceptable recovery.
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