Visible‐Light‐Driven CO2 Reduction Catalyzed by a Dinuclear Nickel Complex

The utilization of synergy between two metal sites in dinuclear metal catalysts for CO 2 reduction remains challenging. Herein, for the first time, we employ a dinuclear nickel complex as a molecular catalyst for visible‐light‐driven CO 2 reduction with 99 % selectivity toward CO production. The photocatalytic mechanism was proposed based on the results of electrochemical measurements and fluorescent quenching experiments.