Impact of water matrices on oxidation effects and mechanisms of pharmaceuticals by ultraviolet-based advanced oxidation technologies: A review

The binding between water components (dissolved organic matters, anions and cations) and pharmaceuticals influences the migration and transformation of pollutants. Herein, the impact of water matrices on drug degradation, as well as the electrical energy demands during UV, UV/catalysts, UV/O3, UV/H2O2-based, UV/persulfate and UV/chlorine processes were systemically evaluated. The enhancement effects of water constituents are due to the powerful reactive species formation, the recombination reduction of electrons and holes of catalyst and the catalyst regeneration; the inhibition results from the light attenuation, quenching effects of the excited states of target pollutants and reactive species, the stable complexations generation and the catalyst deactivation. The transformation pathways of the same pollutant in various AOPs have high similarities. At the same time, each oxidant also can act as a special nucleophile or electrophile, depending on the functional groups of the target compound. The electrical energy per order (EEO) of drugs degradation may follow the order of EEOUV > EEOUV/catalyst > EEOUV/H2O2 > EEOUV/PS > EEOUV/chlorine or EEOUV/O3. Meanwhile, it is crucial to balance the cost-benefit assessment and toxic by-products formation, and the comparison of the contaminant degradation pathways and productions in the presence of different water matrices is still lacking.