化学
固定相
萃取(化学)
金属有机骨架
固相萃取
多孔性
相(物质)
色谱法
生化工程
工艺工程
纳米技术
有机化学
吸附
工程类
材料科学
作者
Anna A. Kotova,Didier Thiébaut,Jérôme Vial,Antoine Tissot,Christian Serre
标识
DOI:10.1016/j.ccr.2021.214364
摘要
Analytical chemistry is involved in many areas of human activities for the separation of complex mixtures. One of the most common and popular technique is chromatography, which is based on different affinities of the compounds with the mobile and stationary phases. However, with the progress of chemical industry, modern stationary phases are not always able to solve the upcoming tasks. Thus, there is a demand in the development of new materials possessing advantages over commercial ones. Porous hybrid solids such as Metal-organic frameworks (MOFs) are good candidates to solve this problem due to their unique physico-chemical properties. This review focuses on the implementation of native and modified MOFs and the comparison of their application in gas, liquid chromatography, and sample preparation (solid-phase extraction). We discuss the progresses and main results obtained until now, summarize the main advantages and current limitations of each application and discuss the possible future developments of these solids.
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