In situ growth of hierarchical bimetal-organic frameworks on nickel-iron foam as robust electrodes for the electrocatalytic oxygen evolution reaction

Evidence shows that self-supported electrocatalysts are crucial role to solving environmental and energy issues. In this study, self-supported 2D metal-organic framework (MOF) nanosheets grown in situ on nickel-iron foam (NFF) were prepared by a one-step solvothermal process. The hierarchical nanostructure possesses a high specific surface area and abundant metal sites, which are beneficial for electrocatalytic reactions. In the electrocatalytic oxygen evolution reaction (OER), the optimal NiFe(20Ni)-MOF/NFF can drive current densities of 10, 50 and 100 mA cm-2 at small overpotentials of 226, 277 and 294 mV, respectively. According to the characterization results, the OER performance is improved by the synergistic action of bimetals and the generation of hydroxides/oxyhydroxides. This work provides new insights into fabricating self-supported MOF-based electrodes for water splitting that are simple and highly efficient.