Microstructure and mechanical properties of Al–Co–Cr–Fe–Ni–(Nb–Ti) high entropy alloys

The structure and mechanical properties of non-equiatomic Al8Co30Cr18Fe9Ni31Nb4, Al8Co30Cr18Fe9Ni31Nb2Ti2 and Al8Co30Cr18Fe9Ni31Ti4 high entropy alloys (HEAs) were investigated using X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM), hardness and tensile testing. TEM and XRD analyses revealed the formation of γ''-Ni3Nb/γ (FCC), double FCC and γ'-Ni3Al/γ (FCC) structure for as-cast Al8Co30Cr18Fe9Ni31Nb4, Al8Co30Cr18Fe9Ni31Nb2Ti2 and Al8Co30Cr18Fe9Ni31Ti4 HEAs, respectively. The hardness and yield strength values were found to increase with the addition of Nb while the ductility of alloys increased with the increase in Ti concentration, significantly. The as-cast Al8Co30Cr18Fe9Ni31Ti4 alloy exhibited an excellent combination of ultimate tensile strength of 844 MPa and an elongation of 29.8% due to the coherent phase relation between γ’ precipitates and γ matrix. The fractured surfaces of as-cast Al8Co30Cr18Fe9Ni31Nb4, Al8Co30Cr18Fe9Ni31Nb2Ti2 and Al8Co30Cr18Fe9Ni31Ti4 HEAs showed typical dimple type ductile fracture under tension test.