电泳剂
亲核细胞
化学
激进的
比例(比率)
计算化学
光化学
有机化学
催化作用
物理
量子力学
作者
Freija De Vleeschouwer,Véronique Van Speybroeck,Michel Waroquier,Pau̧l Geerlings,Frank De Proft
出处
期刊:Organic Letters
[American Chemical Society]
日期:2007-06-09
卷期号:9 (14): 2721-2724
被引量:419
摘要
Radicals can be regarded as electrophilic/nucleophilic, depending on their tendency to attack sites of relatively higher/lower electron density. In this paper, an electrophilicity scale, global as well as local, and a nucleophilicity scale for 35 radicals is reported. The global electrophilicity scale correlates well with the nucleophilicity scale, suggesting that these concepts are inversely related.
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