MOF‐derived Carbon‐Based Materials for Energy‐Related Applications

Abstract New carbon‐based materials (CMs) are recommended as attractively active materials due to their diverse nanostructures and unique electron transport pathways, demonstrating great potential for highly efficient energy storage applications, electrocatalysis, and beyond. Among these newly reported CMs, metal–organic framework (MOF)‐derived CMs have achieved impressive development momentum based on their high specific surface areas, tunable porosity, and flexible structural‐functional integration. However, obstacles regarding the integrity of porous structures, the complexity of preparation processes, and the precise control of active components hinder the regulation of precise interface engineering in CMs. In this context, this review systematically summarizes the latest advances in tailored types, processing strategies, and energy‐related applications of MOF‐derived CMs and focuses on the structure‐activity relationship of metal‐free carbon, metal‐doped carbon, and metallide‐doped carbon. Particularly, the intrinsic correlation and evolutionary behavior between the synergistic interaction of micro/nanostructures and active species with electrochemical performances are emphasized. Finally, unique insights and perspectives on the latest relevant research are presented, and the future development prospects and challenges of MOF‐derived CMs are discussed, providing valuable guidance to boost high‐performance electrochemical electrodes for a broader range of application fields.