Low-valence platinum single atoms in sulfur-containing covalent organic frameworks for photocatalytic hydrogen evolution

This study focuses on optimizing catalytic activity in photocatalytic hydrogen evolution reaction by precisely designing and modulating the electronic structure of metal single atoms. The catalyst, denoted as PtSA@S-TFPT, integrates low-valence platinum single atoms into sulfur-containing covalent organic frameworks. The robust asymmetric four-coordination between sulfur and platinum within the framework enables a high platinum loading of 12.1 wt%, resulting in efficient photocatalytic hydrogen production activity of 11.4 mmol g