Synthesis of magnetic sodium lignosulfonate hydrogel(Fe3O4@LS) and its adsorption behavior for Cd2+ in wastewater

Heavy metal pollution is becoming increasingly serious. Heavy metal pollutants are nonbiodegradable and can be bioenriched through the food chain, and thus, they greatly threaten the environment and human health. Hydrogels, as an ideal adsorbent, have been widely used to treat heavy metal industrial wastewater. Sodium lignosulfonate hydrogel (LS) was prepared by free-radical grafting copolymerization, and nano-Fe3O4 particles were loaded in LS by an in-situ precipitation method (Fe3O4@LS). The magnetic properties and adsorption capacity of Fe3O4@LS are closely related to the load capacity of Fe3O4. XRD, FTIR, XPS, SEM, TEM, BET, and TGA analyses of the materials were performed. Subsequently, the removal effect of the typical pollutant Cd2+ in heavy metal-polluted water was studied with Fe3O4@LS as the adsorbent. The influences of the Fe3O4@LS dosage and initial pH were investigated, and the adsorption kinetics and thermodynamics were further explored and discussed. Finally, the adsorption mechanism of Fe3O4@LS on Cd2+ was obtained. Results show that Fe3O4@LS has a more stable spatial network structure than LS, and the pore size, specific surface area and active sites increase. The maximum adsorption capacity can reach 88.00 mg/g when pH = 6 and the dosage of Fe3O4@LS is 1000 mg/L. The adsorption of Cd2+ by Fe3O4@LS conforms to pseudosecond-order kinetics and the Temkin isothermal adsorption model. Further mechanistic investigations show that the sorption of Cd2+ on Fe3O4@LS is mainly attributed to surface complexation, electrostatic attraction and coprecipitation. The coexistence of cations in water will inhibit the adsorption of Fe3O4@LS. Fe3O4@LS has superparamagnetism and a good response to an external magnetic field. The adsorption rate can still reach >60 % after four elutions with NaCl as the eluent. This material can be reused and has good application potential.