渗透力
反向电渗析
膜
纳米流体学
电渗析
功率密度
能量转换效率
化学
离子键合
离子
多孔性
化学工程
材料科学
磁导率
纳米技术
正渗透
功率(物理)
反渗透
光电子学
有机化学
热力学
工程类
生物化学
物理
作者
Chien‐Wei Chu,Amalia Rizki Fauziah,Li‐Hsien Yeh
标识
DOI:10.1002/anie.202303582
摘要
The design of ion-selective membranes is the key towards efficient reverse electrodialysis-based osmotic power conversion. The tradeoff between ion selectivity (output voltage) and ion permeability (output current) in existing porous membranes, however, limits the upgradation of power generation efficiency for practical applications. Thus, we provide the simple guidelines based on fundamentals of ion transport in nanofluidics for promoting osmotic power conversion. In addition, we discuss strategies for optimizing membrane performance through analysis of various material parameters in membrane design, such as pore size, surface charge, pore density, membrane thickness, ion pathway, pore order, and ionic diode effect. Lastly, a perspective on the future directions of membrane design to further maximize the efficiency of osmotic power conversion is outlined.
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