Multifunctional soybean protein isolate-graft-carboxymethyl cellulose composite as all-biodegradable and mechanically robust mulch film for “green” agriculture

Multifunctional mulch films with robust mechanical behaviors of biopolymer-based biodegradable mulch materials were highly demanded in promoting the development of "green" agriculture. Herein, a sort of mechanically robust and all-biodegradable soybean protein isolate-graft‑sodium carboxymethyl cellulose composite mulch film was innovatively proposed through the amidation reactions between -COOH on protonated sodium carboxymethyl cellulose and -NH2 on soybean protein isolate. Arising from the reinforced intermolecular interactions upon chemical covalent bonds and physical hydrogen bonds, the maximum tensile strength and the elongation at break were increased from 10.61 MPa and 20.67 % for sodium carboxymethyl cellulose film to 42.15 MPa and 24.8 % for the optimized soybean protein isolate-graft‑sodium carboxymethyl cellulose composite mulch film, respectively. In addition, experimental results showed that the optimized soybean protein isolate-graft‑sodium carboxymethyl cellulose composite mulch film possesses soil moisture retention and controlled urea release properties. When employed as mulch film in practice, the cabbage seed presents higher germination when soil was covered with this versatile mulch film compared to commercial low-density polyethylene mulch film. Our discoveries build a prototype for the manufacture of eco-friendly mulch films with high mechanical strength, soil moisture retention, controlled urea release features.