材料科学
水溶液
电化学
阴极
锌
离子
钙钛矿(结构)
扩散
氧化物
无机化学
电流密度
电极
化学工程
冶金
化学
物理化学
有机化学
工程类
物理
热力学
量子力学
作者
Ping Lei,Jiehui Liu,Shuyuan Zhuge,Zhe Lü
标识
DOI:10.1016/j.matlet.2022.133575
摘要
Aqueous Zinc ion batteries (AZIBs) is well considered as a potential candidate with green, safety and low cost for large-scale grid storage. Perovskite oxide SrVO3 can be used as the cathode material for AZIBs due to its high electrically conductive. Therefore, the SrVO3 as a novel cathode material by sol–gel route was prepared to investigate the electrochemical performance. The SrVO3 exhibits outstanding rate capability with high reversible capacities of 142.7 mA h g−1 at 200 mA g−1, 134.9 mA h g−1 at 300 mA g−1, and 105.3 mA h g−1 at 2000 mA g−1 are ascribed to the fast diffusion reaction kinetics. Moreover, the cycling performance of SrVO3 was delivered with capacity retention of 79 % after 3000 cycles at a current density of 2000 mA g−1 in the 0.4–1.8 V voltage window. This work provides a new prospect for the development of perovskite-type cathode materials for AZIBs.
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