High‐Performance Liquid Crystalline Polymer for Intrinsic Fire‐Resistant and Flexible Triboelectric Nanogenerators

Flammability is a great challenge in the fields of electronics. The emergence of triboelectric nanogenerators (TENGs) provides a safe way to harvest environmentalally friendly energy and convert it into more secure power sources. Especially, polymer-based TENGs significantly accelerate the practical application of self-powered flexible electronics. However, most of the existing polymeric materials for TENGs are easily flammable and melt, dripping, in a fire scenario, and cannot be reused after combustion, which greatly limits the application of TENGs under extreme conditions. Herein, a fire-resistant TENG based on all-aromatic liquid crystalline poly(aryl ether ester) (LCPAEE ) synthesized via simple and efficient one-pot melt polycondensation is reported. The highly rigid main chain of LCPAEE endows the LCP-TENG with outstanding anti-dripping, temperature- and fire-resistance. The resultant LCP-TENG exhibits excellent electrical output performance, which is attributed to the high dielectric constant (ε' = 4.8) and fibrous-structured morphology of LCPAEE . The device can maintain over 65% of open-circuit voltage even after 16 s combustion (≈520 °C). Consequently, this work offers a novel strategy for tailoring the TENGs toward a secure power generator and electronics with fire hazard reduction, and potential application in firefighting, personal protection, and other extreme temperature environments.