Two Different Chiral Groups Based Thermally Activated Delayed Fluorescence Materials for Circularly Polarized OLEDs

Circularly polarized organic light‐emitting diodes (CP‐OLEDs) hold significant promise for applications in 3D displays due to the ability to generate circularly polarized luminescence (CPL) directly. In this study, two pairs of circularly polarized thermally activated delayed fluorescence (CP‐TADF) enantiomers, named RR/SS‐ONCN and RS/SR‐ONCN, were synthesized by integrating two distinct chiral groups into the dicyanobenzene unit. The RR/SS‐ONCN and RS/SR‐ONCN enantiomers show CPL properties with dissymmetry photoluminescence factors (|gPL|) of 1.3 × 10‐3 and 2.0 × 10‐3 in doped films, respectively. Notably, RR/SS‐ONCN exhibit higher |gPL| values than that of RS/SR‐ONCN, especially in doped films, indicating that when the configurations of the two chiral groups are identical, the |gPL| value of the CP‐TADF materials can be enhanced, demonstrating a certain stacking effect. Moreover, the corresponding CP‐OLEDs demonstrate good performances, achieving maximum external quantum efficiencies of up to 21.9% and notable CP electroluminescence with |gEL| factors of up to 1.0 × 10‐3.