三乙烯四胺
化学
传质
溶剂
胺气处理
吸收(声学)
烟气
化学工程
无机化学
有机化学
色谱法
材料科学
复合材料
工程类
作者
Shihan Zhang,Yao Shen,Peijing Shao,Jianmeng Chen,Lidong Wang
标识
DOI:10.1021/acs.est.7b05936
摘要
The main issue related to the deployment of the amine-based absorption process for CO2 capture from flue gas is its intensive energy penalty. Therefore, this study screened a novel biphasic solvent, comprising a primary amine e.g., triethylenetetramine (TETA) and a tertiary amine e.g., N,N-dimethylcyclohexylamine (DMCA), to reduce the energy consumption. The TETA-DMCA blend exhibited high cyclic capacity of CO2 absorption, favorable phase separation behavior, and low regeneration heat. Kinetic analysis showed that the gas- and liquid-side mass transfer resistances were comparable in the lean solution of TETA-DMCA at 40 °C, whereas the liquid-side mass transfer resistance became dominant in the rich solution. The rate of CO2 absorption into TETA-DMCA (4 M, 1:3) solution was comparable to 5 M benchmark monoethanolamine (MEA) solution. Based on a preliminary estimation, the regeneration heat with TETA-DMCA could be reduced by approximately 40% compared with that of MEA. 13C NMR analysis revealed that the CO2 absorption into TETA-DMCA was initiated by the reaction between CO2 and TETA via the zwitterion mechanism, and DMCA served as a CO2 sinker to regenerate TETA, resulting in the transfer of DMCA from the upper to lower phase. The proposed TETA-DMCA solvent may be a suitable candidate for CO2 capture.
科研通智能强力驱动
Strongly Powered by AbleSci AI