硅氢加成
区域选择性
马尔科夫尼科夫法则
化学
铱
范围(计算机科学)
催化作用
表面改性
有机化学
组合化学
计算机科学
物理化学
程序设计语言
作者
Xingze Xie,Xueyan Zhang,Haoyu Yang,Xin Ji,Jianing Li,Shengtao Ding
标识
DOI:10.1021/acs.joc.8b02838
摘要
Highly efficient and general Ir-catalyzed hydrosilylation of unactivated alkenes with excellent anti-Markovnikov regioselectivity was described. A broad scope of hydrosilylated products were synthesized economically and conveniently from commercially or naturally available compounds, which provides versatile valuable precursors for organic and medicinal studies.
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