膜
质子交换膜燃料电池
聚合物
材料科学
支化(高分子化学)
合成膜
高分子化学
燃料电池
化学工程
化学稳定性
乙醚
电解质
Nafion公司
有机化学
化学
复合材料
电化学
物理化学
电极
工程类
生物化学
作者
Sivasubramaniyan Neelakandan,Li Wang,Boping Zhang,Jiangpeng Ni,Meishao Hu,Chunmei Gao,Wai‐Yeung Wong,Lei Wang
标识
DOI:10.1080/15583724.2021.1964524
摘要
Recent progress on branched polymer membranes as electrolyte materials for proton exchange membrane fuel cell (PEMFC) applications has attracted interest due to the limitations of commercially available Nafion® membranes. Branched polymer membranes have shown improved chemical stability, proton conductivity, and good solubility. The branching degree and the structure of the branching agent have an essential correlation with the characteristics of the polymer membranes. This review presents the most recent and promising design strategies and characteristics of branched polymers as proton exchange membranes for both low- and high-temperature proton exchange membrane fuel cells. Recent advances in branched polymers are summarized, including branched sulfonated poly(aryl ether)s, branched sulfonated polyimides, branched polybenzimidazoles, etc. The remaining challenges and prospects in proton exchange membranes are also discussed.
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