Self-adhesive and anti-fatigue cellulose-polyacrylate ionogels prepared by ultraviolet curing used as biopotential electrodes

Conductive hydrogels have been extensively studied because of flexibility and skin-like capability to be used as biopotential electrodes for wearable health monitoring. However, they may suffer from poor mechanical properties and stability problems when used in practical applications caused by water evaporation. Herein, we prepared self-adhesive, transparent, flexible and robust ionic gels that can conformal contact with the skin used as biopotential electrodes for precise health monitoring. Cellulose based iogels were prepared by dissolving cellulose using [Bmim]Cl at 100 °C followed by in situ Ultraviolet light photopolymerization of acrylic acid by adding a mixture of acrylic acid and 2-hydroxy-2-methylpropiophenone. Cellulose/polyacrylic acid-based ionic gels-2 (BCELIG-2) has a Young's modulus of 0.2 MPa, a strain at break of 226 %, a modulus of elasticity of 0.1 MPa, and a toughness of 22.5 MJ m-3. Fixing the strain at 40 %, the ionic gels can recover to their original length after ten tensile-unloading cycles. They can accurately detect subtle physical motions such as arterial pulsations, which can provide important cardiovascular information.