丙胺
酰胺
催化作用
胺气处理
化学
小学(天文学)
产量(工程)
选择性
组合化学
X射线光电子能谱
有机化学
化学工程
材料科学
物理
工程类
天文
冶金
作者
Wanjun Guo,Qineng Xia,Hongyan Jia,Yong Guo,Xiaohui Liu,Pan Hu,Yangang Wang,Yanqin Wang
标识
DOI:10.1002/asia.202101256
摘要
Amines are an important class of compounds in natural products and medicines. The universal availability of amides provides a potential way for the synthesis of amines. Herein, Ru/Nb2 O5 catalyst is demonstrated to be highly efficient and stable for the selective hydrogenation of propionamide to propylamine (as a model reaction), with up to 91.4% yield of propylamine under relatively mild conditions. Results from XPS analyses, CO chemisorption, TEM images and DRIFTS spectra revealed that the unique properties of Nb2 O5 can effectively activate the C=O group of amides, and the smaller Ru particles on Nb2 O5 could further promote the activation, leading to superior catalytic performance of Ru/Nb2 O5 for amide hydrogenation. Meanwhile, reducing the surface acidity of Nb2 O5 can greatly inhibit the side reactions to by-products, and further enhance the selectivity to amine. Moreover, this catalytic system is also applicable for the hydrogenation of a variety of amides and provides high potential for the industrial production of primary amines from amides.
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