Ni-Catalyzed Regioselective and Site-divergent Reductive Arylalkylations of Allylic Amines

A Ni-catalyzed cross-electrophile regioselective and site-divergent 1,2- and 1,3-arylalkylations of allylic amines has been developed, representing the first controllable migratory difunctionalization of alkenes under reductive conditions.