多金属氧酸盐
材料科学
离子液体
光催化
上部结构
氨
化学工程
吸附
催化作用
有机化学
化学
工程类
海洋学
地质学
作者
Xiangjiao Gong,Wenkai Teng,Wei Liu,Hang Xiao,He Li,Honghui Ou,Guidong Yang
标识
DOI:10.1002/adma.202412924
摘要
Designing a reaction system that integrates reactant capture and transformation in an artificial photosynthesis system to achieve high reaction efficiency remains challenging. Here, an ionic liquid (IL) -polyoxometalate (POM) superstructure photocatalyst (P2HPMo) is reported, where the anisotropy of the superstructure is allowed by adjusting the alkyl chain lengths of ILs. Experimental data and theoretical simulation show that ILs and POM serve as the "sucker" and "reactor" of the reaction system to capture and transform the reactants, respectively. In particular, the addition of quaternary phosphorous IL cations is not only conducive to the adsorption of N
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