Effect of Additive Content on Texture Evolution and Mechanical Properties of Si3n4 Ceramics Prepared by Hot Pressing

The purpose of this research is to investigate influence of additive content on sintering behavior, texture evolution and mechanical properties of Si3N4 ceramics systematically. Si3N4 ceramics with different additive contents are prepared by hot pressing at 1750 °C for 1h. XRD analysis confirms that the densification process is dominated by particle rearrangement instead of phase transformation. Grain morphology characterization demonstrates that additive content affects relative amount between textured [[EQUATION]]-Si3N4 grains and [[EQUATION]]-Si3N4 nuclei during initial sintering. During subsequent sintering, [[EQUATION]]-Si3N4 nuclei surrounded by residual liquid phase elongated randomly, and then weaken texture degree of Si3N4 ceramics. The texture degree of Si3N4 ceramics decreases first and then increases as additives increase steadily. Based on the CTE misfit model and the stochastic model of crack propagation, texture degree, residual stress and grain size have a synergistic effect on crack propagation behavior of [[EQUATION]]-Si3N4 ceramics. The outstanding flexural strength (1096 MPa) and fracture toughness (10.61 MPa[[EQUATION]]m1/2) is achieved in hot pressed SN21 with a relatively high texture degree (fL=0.213).