Multi-atom cluster catalysts for efficient electrocatalysis

催化作用 星团(航天器) 电催化剂 电化学 Atom(片上系统) 纳米技术 化学 电化学能量转换 组合化学 化学物理 材料科学 物理化学 计算机科学 电极 有机化学 嵌入式系统 程序设计语言
作者
Libo Sun,Vikas Reddu,Xin Wang
出处
期刊:Chemical Society Reviews [The Royal Society of Chemistry]
卷期号:51 (21): 8923-8956 被引量:100
标识
DOI:10.1039/d2cs00233g
摘要

Multi-atom cluster catalysts have turned out to be novel heterogeneous catalysts with atomic dispersion for electrochemical energy applications. Beyond a simple combination of single-atom catalysts, they could offer boosted activity as a result of the synergistic effects between adjacent atoms. Meanwhile, the multiple active sites in the catalytic center may render them versatile binding modes toward adsorbates and provide an opportunity for catalyzing complex reactions with diverse products. Herein, a comprehensive review of the recent development of multi-atom cluster catalysts for electrochemical energy applications is provided. Specifically, the origin of synergistic effects in multi-atom cluster catalysts and related modulation methods are illustrated and summarized. The introduction of multi-atom cluster catalysts to circumvent the scaling relationships as well as their potential for developing new descriptors is then discussed. Subsequently, the methods for fabricating multi-atom cluster catalysts and related characterization techniques are reviewed. This is followed by the discussion of their application in key electrochemical reactions such as water splitting, oxygen reduction, and carbon dioxide/monoxide reduction, as well as the real-time techniques for their mechanistic study. Finally, the future challenges and opportunities concerning the improvement of multi-atom cluster catalysts are outlined, which are essential to make such electrocatalysts viable for electrochemical energy conversion.
最长约 10秒,即可获得该文献文件

科研通智能强力驱动
Strongly Powered by AbleSci AI
更新
大幅提高文件上传限制,最高150M (2024-4-1)

科研通是完全免费的文献互助平台,具备全网最快的应助速度,最高的求助完成率。 对每一个文献求助,科研通都将尽心尽力,给求助人一个满意的交代。
实时播报
橙汁完成签到,获得积分10
1秒前
lshu文发布了新的文献求助10
2秒前
2秒前
3秒前
阿勒泰发布了新的文献求助10
3秒前
zhong完成签到,获得积分10
3秒前
3秒前
JoaquinH发布了新的文献求助10
4秒前
orixero应助kante采纳,获得10
4秒前
Dpd完成签到,获得积分10
4秒前
jbhb发布了新的文献求助10
5秒前
拼搏飞柏发布了新的文献求助10
6秒前
6秒前
华仔应助跳跃尔琴采纳,获得10
8秒前
风趣的亦巧完成签到,获得积分10
8秒前
小白完成签到,获得积分10
8秒前
风趣采白发布了新的文献求助10
8秒前
天涯发布了新的文献求助10
8秒前
9秒前
兴奋一斩发布了新的文献求助10
9秒前
瘦子张完成签到,获得积分20
9秒前
红汤加煎蛋完成签到,获得积分10
10秒前
小马甲应助雨碎寒江采纳,获得10
10秒前
思源应助往昔采纳,获得10
10秒前
ZW完成签到,获得积分20
11秒前
11秒前
hibye完成签到,获得积分10
13秒前
13秒前
夜幕云端发布了新的文献求助10
14秒前
PPRer完成签到,获得积分10
14秒前
爆米花应助李哈哈采纳,获得10
14秒前
14秒前
打打应助jenniefer采纳,获得10
14秒前
风趣的烨磊完成签到,获得积分10
14秒前
Ava应助风趣采白采纳,获得10
15秒前
15秒前
16秒前
王巧巧完成签到,获得积分10
16秒前
pluto应助zll采纳,获得10
16秒前
小蘑菇应助zll采纳,获得10
16秒前
高分求助中
The ACS Guide to Scholarly Communication 2500
Sustainability in Tides Chemistry 2000
Pharmacogenomics: Applications to Patient Care, Third Edition 1000
Studien zur Ideengeschichte der Gesetzgebung 1000
TM 5-855-1(Fundamentals of protective design for conventional weapons) 1000
Threaded Harmony: A Sustainable Approach to Fashion 810
《粉体与多孔固体材料的吸附原理、方法及应用》(需要中文翻译版,化学工业出版社,陈建,周力,王奋英等译) 500
热门求助领域 (近24小时)
化学 医学 生物 材料科学 工程类 有机化学 生物化学 物理 内科学 纳米技术 计算机科学 化学工程 复合材料 基因 遗传学 催化作用 物理化学 免疫学 量子力学 细胞生物学
热门帖子
关注 科研通微信公众号,转发送积分 3083403
求助须知:如何正确求助?哪些是违规求助? 2736768
关于积分的说明 7542379
捐赠科研通 2386033
什么是DOI,文献DOI怎么找? 1265316
科研通“疑难数据库(出版商)”最低求助积分说明 613035
版权声明 597816