限制电流
努森扩散
扩散
微型多孔材料
扩散层
电解质
气体扩散
化学
氧气输送
质子交换膜燃料电池
材料科学
分析化学(期刊)
化学工程
氧气
热力学
图层(电子)
膜
复合材料
多孔性
色谱法
有机化学
电化学
电极
物理化学
物理
工程类
生物化学
作者
Daniel R. Baker,D. A. Caulk,K.C. Neyerlin,Michael W. Murphy
出处
期刊:Journal of The Electrochemical Society
[The Electrochemical Society]
日期:2009-01-01
卷期号:156 (9): B991-B991
被引量:403
摘要
Limiting current measurements in a polymer electrolyte membrane (PEM) fuel cell are used to separate the oxygen-transport resistance into individual component parts. By varying the thicknesses of the diffusion medium (DM) and the microporous layer in different cell builds, the total transport resistance is separated into contributions from flow channels, DM, microporous layer, and all other sources. By varying the pressure, the transport resistance is separated into a pressure-dependent component (intermolecular gas diffusion) and a pressure-independent component (Knudsen diffusion or transport through ionomer/liquid water layers). In addition to oxygen diffusion in an anisotropic gas diffusion layer, the analysis accounts for coupled convective diffusion and reactant depletion in the flow channels. The present work is limited to conditions when no condensation occurs inside the cell. The analysis is applied to a large body of limiting current data collected on Toray diffusion media, both plain and treated with poly(tetrafluoroethylene) (PTFE), with and without a microporous layer. Effective diffusion coefficients obtained from these methods for plain Toray papers compare reasonably well with independent ex situ measurements of water vapor diffusion through the same materials.
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