Polymer/Boron Nitride Nanocomposite Materials for Superior Thermal Transport Performance

Angewandte Chemie International EditionVolume 51, Issue 26 p. 6498-6501 Communication Polymer/Boron Nitride Nanocomposite Materials for Superior Thermal Transport Performance† Wei-Li Song, Wei-Li Song Department of Chemistry and Laboratory for Emerging Materials and Technology, Clemson University, Clemson, SC 29634 (USA)Search for more papers by this authorPing Wang, Ping Wang Department of Chemistry and Laboratory for Emerging Materials and Technology, Clemson University, Clemson, SC 29634 (USA)Search for more papers by this authorDr. Li Cao, Dr. Li Cao Department of Chemistry and Laboratory for Emerging Materials and Technology, Clemson University, Clemson, SC 29634 (USA)Search for more papers by this authorAnkoma Anderson, Ankoma Anderson Department of Chemistry and Laboratory for Emerging Materials and Technology, Clemson University, Clemson, SC 29634 (USA)Search for more papers by this authorDr. Mohammed J. Meziani, Dr. Mohammed J. Meziani Department of Chemistry and Laboratory for Emerging Materials and Technology, Clemson University, Clemson, SC 29634 (USA)Search for more papers by this authorAndrew J. Farr, Andrew J. Farr Department of Chemistry and Laboratory for Emerging Materials and Technology, Clemson University, Clemson, SC 29634 (USA)Search for more papers by this authorProf. Dr. Ya-Ping Sun, Corresponding Author Prof. Dr. Ya-Ping Sun [email protected] Department of Chemistry and Laboratory for Emerging Materials and Technology, Clemson University, Clemson, SC 29634 (USA)Department of Chemistry and Laboratory for Emerging Materials and Technology, Clemson University, Clemson, SC 29634 (USA)Search for more papers by this author Wei-Li Song, Wei-Li Song Department of Chemistry and Laboratory for Emerging Materials and Technology, Clemson University, Clemson, SC 29634 (USA)Search for more papers by this authorPing Wang, Ping Wang Department of Chemistry and Laboratory for Emerging Materials and Technology, Clemson University, Clemson, SC 29634 (USA)Search for more papers by this authorDr. Li Cao, Dr. Li Cao Department of Chemistry and Laboratory for Emerging Materials and Technology, Clemson University, Clemson, SC 29634 (USA)Search for more papers by this authorAnkoma Anderson, Ankoma Anderson Department of Chemistry and Laboratory for Emerging Materials and Technology, Clemson University, Clemson, SC 29634 (USA)Search for more papers by this authorDr. Mohammed J. Meziani, Dr. Mohammed J. Meziani Department of Chemistry and Laboratory for Emerging Materials and Technology, Clemson University, Clemson, SC 29634 (USA)Search for more papers by this authorAndrew J. Farr, Andrew J. Farr Department of Chemistry and Laboratory for Emerging Materials and Technology, Clemson University, Clemson, SC 29634 (USA)Search for more papers by this authorProf. Dr. Ya-Ping Sun, Corresponding Author Prof. Dr. Ya-Ping Sun [email protected] Department of Chemistry and Laboratory for Emerging Materials and Technology, Clemson University, Clemson, SC 29634 (USA)Department of Chemistry and Laboratory for Emerging Materials and Technology, Clemson University, Clemson, SC 29634 (USA)Search for more papers by this author First published: 15 May 2012 https://doi.org/10.1002/anie.201201689Citations: 341 † Financial support from the Air Force Office of Scientific Research (AFOSR) through the program of Dr. Charles Lee is gratefully acknowledged. W.-L.S. was a visiting student from School of Materials Science and Engineering (the group of Prof. Mao-Sheng Cao) at Beijing Institute of Technology with a fellowship provided by the China Scholarship Council. L.C. was supported by a Susan G. Komen for the Cure Postdoctoral Fellowship, and A.A. and A.J.F. by South Carolina Space Grant Consortium through a Graduate Research Fellowship and the Palmetto Academy Program, respectively. M.J.M. was on leave from Department of Chemistry/Physics, Northwest Missouri State University. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Boron nitride nanosheets were dispersed in polymers to give composite films with excellent thermal transport performances approaching the record values found in polymer/graphene nanocomposites. Similarly high performance at lower BN loadings was achieved by aligning the nanosheets in poly(vinyl alcohol) matrix by simple mechanical stretching (see picture). References 1A. K. Geim, K. S. Novoselov, Nat. Mater. 2007, 6, 183. 2C. N. R. Rao, A. Sood, K. Subrahmanyam, A. Govindaraj, Angew. Chem. 2009, 121, 7890; Angew. Chem. Int. Ed. 2009, 48, 7752. 3M. J. Allen, V. C. Tung, R. B. Kaner, Chem. Rev. 2010, 110, 132. 4Y. Zhu, S. Murali, W. Cai, X. Li, J. W. Suk, J. R. Potts, R. S. Ruoff, Adv. Mater. 2010, 22, 3906. 5D. Golberg, Y. Bando, C. C. Tang, C. Y. Zhi, Adv. Mater. 2007, 19, 2413. 6D. R. Dreyer, R. S. Ruoff, C. W. Bielawski, Angew. Chem. 2010, 122, 9524; Angew. Chem. Int. 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