铜
化学
氧化还原
价(化学)
化学计量学
金属
键裂
结晶学
氧化态
无机化学
光化学
物理化学
催化作用
有机化学
作者
Adam P. Cole,David E. Root,Pulakesh Mukherjee,Edward I. Solomon,T. Daniel P. Stack
出处
期刊:Science
[American Association for the Advancement of Science (AAAS)]
日期:1996-09-27
卷期号:273 (5283): 1848-1850
被引量:240
标识
DOI:10.1126/science.273.5283.1848
摘要
The reaction of metal complexes with dioxygen (O2) generally proceeds in 1:1, 21, or 41 (metal:O2) stoichiometry. A discrete, structurally characterized 31 product is presented. This mixed-valence trinuclear copper cluster, which contains copper in the highly oxidized trivalent oxidation state, exhibits O2 bond scission and intriguing structural, spectroscopic, and redox properties. The relevance of this synthetic complex to the reduction of O2 at the trinuclear active sites of multicopper oxidases is discussed.
科研通智能强力驱动
Strongly Powered by AbleSci AI