Palladium-catalyzed decarboxylative [2 + 3] cyclocarbonylation reactions of [60]fullerene: selective synthesis of [60]fullerene-fused 3-vinylcyclopentan-4-ones and cyclopentane-4-carbaldehydes

A new palladium-catalyzed decarboxylative strategy has been developed toward direct cyclocarbonylation of [60]fullerene, selectively furnishing novel [60]fullerene-fused 3-vinylcyclopentan-4-ones and cyclopentane-4-carbaldehydes.