Palladium‐Catalyzed Asymmetric C(sp2)H Functionalization

Abstract The asymmetric CH activation field has been rapidly expanding research axis. Indeed, implementing the CH activation mindset within the synthesis of chiral molecules opens unprecedented opportunities to access enantiomerically pure compounds rapidly. In particular, the combination of the C(sp2)H activation and stereoselective synthesis turned out to be a versatile and high‐efficient methodology delivering a variety of atropisomeric compounds and also molecules bearing stereogenic centers and planar chirality. In this article, the key concepts and achievements in the field of asymmetric Pd‐catalyzed C(sp 2 )H activation are discussed.