催化作用
制氢
材料科学
化学工程
环境友好型
异质结
硫黄
氢
纳米技术
化学
光电子学
有机化学
生态学
生物
工程类
冶金
作者
Kaiwen Gao,Min Zhou,Yifeng Liu,Shuocheng Wang,Rong Fu,Zhaoyang Wang,Jinghui Guo,Ziang Liu,Hairen Wang,Yan Zhao,Wei Wang
标识
DOI:10.1016/j.jcis.2023.11.140
摘要
Substituting the sluggish oxygen evolution reaction with the sulfur oxidation reaction can significantly reduce energy consumption and eliminate environmental pollutants during hydrogen generation. However, the progress of this technology has been hindered due to the lack of cost-effective, efficient, and durable electrocatalysts. In this study, we present the design and construction of a hierarchical metal sulfide catalyst with a gradient structure comprising nanoparticles, nanosheets, and microparticles. This was achieved through a structure-breaking sulfuration strategy, resulting in a "ball of yarn"-like core/shell CoS/MoS2 microflower with CoS/MoS2/CoS dual-heterojunctions. The difference in work functions between CoS and MoS2 induces an electron polarization effect, creating dual built-in electric fields at the hierarchical interfaces. This effectively modulates the adsorption behavior of catalytic intermediates, thereby reducing the energy barrier for catalytic reactions. The optimized catalyst exhibits outstanding electrocatalytic performance for both the hydrogen evolution reaction and the sulfur oxidation reaction. Remarkably, in the assembled electrocatalytic coupling system, it only requires a cell voltage of 0.528 V at 10 mA cm−2 and maintains long-term durability for over 168 h. This work presents new opportunities for low-cost hydrogen production and environmentally friendly sulfion recycling.
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