电解质
阴极
材料科学
电流密度
溶解
化学物理
电化学
化学工程
分析化学(期刊)
电极
化学
物理
物理化学
量子力学
工程类
色谱法
作者
Huanzhu Lv,Lei Zhou,Qisheng Fang,Jianli Cheng,Jun Mei,Yuanhua Xia,Bin Wang
出处
期刊:Small
[Wiley]
日期:2024-05-28
标识
DOI:10.1002/smll.202312204
摘要
Abstract LiNi 0.8 Mn 0.1 Co 0.1 O 2 with high nickel content plays a critical role in enabling lithium metal batteries (LMBs) to achieve high specific energy density, making them a prominent choice for electric vehicles (EVs). However, ensuring the long‐term cycling stability of the cathode electrolyte interfaces (CEIs), particularly at fast‐charge conditions, remains an unsolved challenge. The decay mechanism associated with CEIs and electrolytes in LMB at high current densities is still not fully understood. To address this issue, in situ Fourier transform infrared (FTIR) is employed to observe the dynamic process of formation/disappearance/regeneration of CEIs during charge and discharge cycles. These dynamic processes further exacerbate the instability of CEIs as current density increases, leading to rupture and dissolution of CEIs and subsequent deterioration in battery performance because of continuous electrolyte reactions. Additionally, the dynamic changes occurring within individual components of CEIs at different cycling stages and various current densities are also discussed. The results demonstrate that excellent capacity retention at small current density is attributed to enrichment of inorganic compounds (Li 2 CO 3 , LiF, etc.) and rendering better stability and smaller expansion of CEIs. The key to achieving excellent electrochemical performance at high current densities lies on protecting CEIs, mainly inorganic components.
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