Organometallic complexes of neodymium: an overview of synthetic methodologies based on coordinating elements

Abstract Organometallic complexes of neodymium have unique coordinating ability to form both micro and macromolecules as well as metal-based polymers. These complexes have been reported in different fields and play a tremendous role in luminescence, catalytic, biological and magnetic applications. So, the current study will comprise all possible routes for the synthesis of organometallic complexes of neodymium. Neodymium complexes have been synthesized of single, double, triple and tetra linkages with H, C, N, O as well as S, B, and X. The detailed synthetic routes have been classified into four categories but in brief, neodymium forms complexes by reacting metal chloride, nitrate or oxide (hydrated or dehydrated) as precursor along with appropriate ligand. Most applied solvents for neodymium complexes were Toluene and THF. These complexes required a range of temperature based on the nature of complexes as well as linkages. The authors have surveyed the research work published through 2011–2020 and provide a comprehensive overview to understand the synthetic routes of organometallic complexes of neodymium.