Double dielectric barrier discharge incorporated with CeO2-Co3O4/γ-Al2O3 catalyst for toluene abatement by a sequential adsorption–discharge plasma catalytic process

介质阻挡放电 甲苯 催化作用 吸附 非热等离子体 化学 化学工程 氧气 材料科学 等离子体 有机化学 电极 物理化学 量子力学 物理 工程类
作者
Shijie Li,Xin Yu,Xiaoqing Dang,Pengyong Wang,Xiangkang Meng,Qi Wang,Hao Hou
出处
期刊:Journal of Cleaner Production [Elsevier BV]
卷期号:340: 130774-130774 被引量:30
标识
DOI:10.1016/j.jclepro.2022.130774
摘要

As a promising technique to remove volatile organic compounds (VOCs), non-thermal plasma (NTP) has been paid much attention recently. However, the practical implementation of NTP is limited owing to its disadvantages such as low mineralization rate, unsatisfactory energy efficiency and the generation of multiple byproducts. Reactor configuration optimization and plasma coupled catalysis are the two alternatives to improve the efficiency of NTP. A packed bed double dielectric barrier discharge (DDBD) system was established and the performance of CeO2-Co3O4 catalysts for toluene abatement was evaluated in a sequential process. It was found that complete toluene removal could be achieved in the DDBD reactor packed with different catalysts. Among them, CeO2-Co3O4 binary catalysts showed higher toluene degradation performance than monometallic samples and Ce1Co3 had the best mineralization rate (89.68%) and energy yield (3.04 g/kWh). The effects of Ce/Co ratio on the structural and redox characteristics of the samples were analyzed by BET, XRD, TEM, XPS and H2-TPR. The superior catalytic activity was attributed to the interplay between Ce and Co species, which created abundant defects and oxygen vacancies and improved the concentration of surface adsorbed oxygen and the reducibility of catalyst. The effects of the relative parameters, such as applied voltage, toluene adsorbed amount and discharge time on the toluene degradation efficiency were also explored. Finally, the toluene decomposition mechanism in the DDBD catalytic system was speculated according to the detected organic products. The findings in this work can provide vital insight in plasma catalytic degradation of VOCs by sequential process.
最长约 10秒,即可获得该文献文件

科研通智能强力驱动
Strongly Powered by AbleSci AI
科研通是完全免费的文献互助平台,具备全网最快的应助速度,最高的求助完成率。 对每一个文献求助,科研通都将尽心尽力,给求助人一个满意的交代。
实时播报
2秒前
天天快乐应助一一采纳,获得10
3秒前
炙热的雪糕完成签到,获得积分10
3秒前
4秒前
心心0521发布了新的文献求助10
6秒前
pluto应助刘济源采纳,获得10
6秒前
FIN应助15采纳,获得10
6秒前
内向士萧发布了新的文献求助10
7秒前
abcdulla777完成签到,获得积分20
7秒前
8秒前
SYLH应助元狩采纳,获得10
9秒前
DUANYALI完成签到,获得积分10
9秒前
12秒前
马玲完成签到,获得积分10
12秒前
12秒前
13秒前
iwwwwwn完成签到,获得积分20
13秒前
123发布了新的文献求助10
13秒前
15完成签到,获得积分10
15秒前
啊露发布了新的文献求助10
16秒前
可乐发布了新的文献求助10
17秒前
17秒前
科研通AI5应助iwwwwwn采纳,获得10
19秒前
20秒前
20秒前
酷波er应助htWu采纳,获得10
22秒前
虚拟的惜筠发布了新的文献求助150
24秒前
烟花应助LONG采纳,获得10
24秒前
粗心的易云完成签到 ,获得积分10
24秒前
24秒前
传奇3应助123采纳,获得30
25秒前
Yuying发布了新的文献求助10
26秒前
也曦完成签到 ,获得积分20
28秒前
28秒前
Saman发布了新的文献求助10
29秒前
31秒前
大个应助wuxunxun2015采纳,获得10
32秒前
33秒前
xdy完成签到 ,获得积分10
34秒前
张楠完成签到,获得积分10
34秒前
高分求助中
【此为提示信息,请勿应助】请按要求发布求助,避免被关 20000
Production Logging: Theoretical and Interpretive Elements 3000
CRC Handbook of Chemistry and Physics 104th edition 1000
Izeltabart tapatansine - AdisInsight 600
Introduction to Comparative Public Administration Administrative Systems and Reforms in Europe, Third Edition 3rd edition 500
Distinct Aggregation Behaviors and Rheological Responses of Two Terminally Functionalized Polyisoprenes with Different Quadruple Hydrogen Bonding Motifs 450
THE STRUCTURES OF 'SHR' AND 'YOU' IN MANDARIN CHINESE 320
热门求助领域 (近24小时)
化学 材料科学 医学 生物 工程类 有机化学 物理 生物化学 纳米技术 计算机科学 化学工程 内科学 复合材料 物理化学 电极 遗传学 量子力学 基因 冶金 催化作用
热门帖子
关注 科研通微信公众号,转发送积分 3761949
求助须知:如何正确求助?哪些是违规求助? 3305642
关于积分的说明 10135083
捐赠科研通 3019747
什么是DOI,文献DOI怎么找? 1658374
邀请新用户注册赠送积分活动 792030
科研通“疑难数据库(出版商)”最低求助积分说明 754783