Recent Advancements in MOF/Biomass and Bio-MOF Multifunctional Materials: A Review

金属有机骨架 纳米技术 可重用性 生物量(生态学) 材料科学 储能 生物分子 生化工程 计算机科学 化学 工程类 有机化学 软件 程序设计语言 功率(物理) 吸附 地质学 物理 海洋学 量子力学
作者
Jie Liu,Yanjun Li,Zhichao Lou
出处
期刊:Sustainability [Multidisciplinary Digital Publishing Institute]
卷期号:14 (10): 5768-5768 被引量:59
标识
DOI:10.3390/su14105768
摘要

Metal–organic frameworks (MOFs) and their derivatives have delivered perfect answers in detection, separation, solving water and electromagnetic pollution and improving catalysis and energy storage efficiency due to their advantages including their highly tunable porosity, structure and versatility. Recently, MOF/biomass, bio-MOFs and their derivatives have gradually become a shining star in the MOF family due to the improvement in the application performance of MOFs using biomass and biomolecules. However, current studies lack a systematic summary of the synthesis and advancements of MOF/biomass, bio-MOFs and their derivatives. In this review, we describe their research progress in detail from the following two aspects: (1) synthesis of MOF/biomass using biomass as a template to achieve good dispersion and connectivity at the same time; (2) preparing bio-MOFs by replacing traditional organic linkers with biomolecules to enhance the connection stability between metal ions/clusters and ligands and avoid the formation of toxic by-products. This enables MOFs to possess additional unique advantages, such as improved biocompatibility and mechanical strength, ideal reusability and stability and lower production costs. Most importantly, this is a further step towards green and sustainable development. Additionally, we showcase some typical application examples to show their great potential, including in the fields of environmental remediation, energy storage and electromagnetic wave absorption.
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