润滑油
润滑
材料科学
摩擦学
润滑性
纳米颗粒
摩擦系数
环境友好型
摩擦改进剂
限制
化学工程
纳米技术
复合材料
机械工程
工程类
生物
生态学
作者
Afrina Khan Piya,Liuquan Yang,A. Al Sheikh Omar,Nazanin Emami,Ardian Morina
出处
期刊:Carbon
[Elsevier]
日期:2024-01-01
卷期号:218: 118742-118742
被引量:1
标识
DOI:10.1016/j.carbon.2023.118742
摘要
Nanoparticles and organic friction modifiers (OFMs) as lubricant additives have shown great potential in friction and wear reduction by forming tribofilms which prevent direct contact at the sliding interface. Potential mechanisms for the formation of these tribofilms remain poorly understood, limiting the ability to optimise the performance of the entire tribosystem. Incorporation of nanoparticles and OFM together in a lubricant could provide a unique solution to enhance frictional and wear properties. In this study, Nanodiamonds (NDs) and Glycerol Monooleate (GMO) have been added to a PAO base oil containing low concentration of Zinc dialkyl dithio-phosphate (ZDDP) to produce a novel lubricant combination that significantly reduces coefficient of friction (COF) and wear. Experimental studies showed that NDs reacted with additives present in the lubricant combination to expedite tribofilm formation. Friction reduction performance can be attributed to the encapsulation of carboxylated NDs due to tribochemical interaction with GMO, their mechanical interlocking in the tribofilm and polishing effect of NDs. The visible presence of NDs in tribofilms and the formation of a thicker tribofilm layer with NDs have been corroborated for the first time in this study. Synergy achieved among NDs, GMO, and low concentration ZDDP to formulate a novel environmentally friendly lubricant with advanced tribological performance has been shown, providing a great potential to develop sustainable tribological solutions for a wide variety of engineering applications.
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