双金属片
吸附
催化作用
纳米颗粒
氢
选择性
化学工程
材料科学
硫化氢
兴奋剂
纳米技术
化学
有机化学
光电子学
冶金
硫黄
工程类
作者
To Thi Nguyet,Dang Thi Thanh Le,Nguyễn Văn Duy,Chu Thi Xuan,Sven Ingebrandt,Xuan Thang Vu,Nguyễn Đức Hòa
出处
期刊:RSC Advances
[The Royal Society of Chemistry]
日期:2023-01-01
卷期号:13 (19): 13017-13029
被引量:19
摘要
As a source of clean energy, hydrogen (H2) is a promising alternative to fossil fuels in reducing the carbon footprint. However, due to the highly explosive nature of H2, developing a high-performance sensor for real-time detection of H2 gas at low concentration is essential. Here, we demonstrated the H2 gas sensing performance of Ag/Pd nanoparticle-functionalized ZnO nanoplates. Bimetallic Ag/Pd nanoparticles with an average size of 8 nm were prepared and decorated on the surface of ZnO nanoplates to enhance the H2 gas sensing performance. Compared with pristine ZnO, the sensor based on ZnO nanoplate doped with Ag/Pd (0.025 wt%) exhibited an outstanding response upon exposure to H2 gas (Ra/Rg = 78 for 500 ppm) with fast response time and speedy recovery. The sensor also showed excellent selectivity for the detection of H2 over the interfering gases (i.e., CO, NH3, H2S, and VOCs). The superior gas sensing of the sensor was dominated by the morphological structure of ZnO, and the synergistic effect of strong adsorption and the optimum catalytic characteristics of the bimetallic Ag/Pd enhances the hydrogen response of the sensors. Thus, bimetallic Ag/Pd-doped ZnO is a promising sensing material for the quantitative determination of H2 concentration towards industrial applications.
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