堆积
共价键
共轭体系
卟啉
共价有机骨架
介孔材料
光化学
化学
可见光谱
红外线的
紫外线
材料科学
有机化学
聚合物
催化作用
光电子学
光学
物理
作者
Atsushi Nagai,Xiong Chen,Xiao Feng,Xuesong Ding,Zhaoqi Guo,Donglin Jiang
标识
DOI:10.1002/anie.201300256
摘要
π in the sky: A squaraine-linked, conjugated two-dimensional porphyrin covalent organic framework (COF; see scheme; C: gray, H: white, N: blue, Cu: red) was synthesized. Owing to the π-conjugated linkage together with the eclipsed stacking of the units, this COF exhibits enhanced chemical and thermal stabilities. It absorbs a broad range of light, from the ultraviolet to the visible, and near-infrared regions, and shows potential as a photocatalyst.
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