Laser dewetting mechanism and antibacterial properties of Cu-Al based medium entropy alloy films

去湿 合金 材料科学 激光器 机制(生物学) 冶金 纳米技术 化学工程 光学 薄膜 物理 工程类 量子力学
作者
J.J. Wang,H.K. Lin,W.S. Chuang,C.Y. Chuang,Yi‐Hsien Lin,J.C. Huang,Ying-Hong Lin
出处
期刊:Journal of Alloys and Compounds [Elsevier BV]
卷期号:903: 163893-163893 被引量:6
标识
DOI:10.1016/j.jallcom.2022.163893
摘要

High entropy alloys (HEAs) have attracted significant interest in recent decades due to their unique microstructures and many favorable properties, including high mechanical strength, good thermal stability and excellent corrosion resistance. In the present study, three Cu-Al based medium entropy alloys (MEAs), namely CuAlAg (CAA), CuAlZn (CAZ) and CuAlV (CAV), are deposited on glass substrates using a high-vacuum sputtering system. The as-sputtered MEA films (MEAFs) are processed by Rapid Thermal Annealing (RTA) for 5 min in order to stabilize their microstructures and are then dewetted using a near infrared (NIR) fiber laser system with various repetition rates, pulse powers and scan speeds to produce nanoparticle structures. Finally, the antibacterial properties of the MEAFs and dewetted films are investigated using three bacterial strains, namely Escherichia coli, Pseudomonas aeruginosa and Staphylococcus aureus. It is shown that the particle size of the dewetted films decreases as the accumulated energy (AE) density increases. The smaller particle size leads to a blue shift of the localized surface plasmon resonance (LSPR) absorption peak wavelength as a result of the greater uniformity of the induced electromagnetic field. In the dewetting process, the Ag and Cu elements of the MEAFs form particles, while the Al atoms are repelled to the bottom or surrounding region of the nanoparticles, and the Zn and V atoms remain on the glass surface. The MEAFs and dewetted films show an antibacterial efficiency of 100% for all three bacterial strains after 24 h. Moreover, the bacterial growth curves indicate that the majority of the bacteria are destroyed within 4–5 h of contact. The antibacterial effect of the MEAFs and dewetted films is attributed to the production of reactive oxygen species (ROS) and the release of metal ions, which collectively destroy the cell membranes and lead to cell shrinkage and death. For all of the MEAFs, the antibacterial performance improves after dewetting as a result of the increased surface contact area provided by the nanoparticles. Overall, the present results confirm the effectiveness of MEAs and dewetted films in realizing thin-film coatings with enhanced antibacterial properties.
最长约 10秒,即可获得该文献文件

科研通智能强力驱动
Strongly Powered by AbleSci AI
更新
PDF的下载单位、IP信息已删除 (2025-6-4)

科研通是完全免费的文献互助平台,具备全网最快的应助速度,最高的求助完成率。 对每一个文献求助,科研通都将尽心尽力,给求助人一个满意的交代。
实时播报
刚刚
zxzb完成签到,获得积分10
2秒前
苹果萧完成签到 ,获得积分10
5秒前
宋江他大表哥完成签到,获得积分10
5秒前
able发布了新的文献求助10
5秒前
王先生完成签到 ,获得积分10
6秒前
H.发布了新的文献求助10
6秒前
luoluo完成签到,获得积分10
7秒前
7秒前
高分子完成签到,获得积分10
7秒前
yian发布了新的文献求助10
8秒前
yar应助体贴凌柏采纳,获得10
9秒前
自由的雪一完成签到,获得积分10
9秒前
Ava应助李振博采纳,获得200
9秒前
JW发布了新的文献求助10
10秒前
无限的千凝完成签到 ,获得积分10
11秒前
CipherSage应助YeeYee采纳,获得10
11秒前
11秒前
Ander完成签到 ,获得积分10
12秒前
化白完成签到,获得积分10
13秒前
H.完成签到,获得积分10
13秒前
chuzihang完成签到 ,获得积分10
13秒前
科研小狗完成签到,获得积分10
19秒前
11完成签到,获得积分10
20秒前
柏林寒冬应助QAQ采纳,获得10
22秒前
Flynn完成签到 ,获得积分10
24秒前
25秒前
25秒前
BZPL完成签到,获得积分10
26秒前
LANER完成签到 ,获得积分10
26秒前
26秒前
ww完成签到 ,获得积分10
26秒前
拉布拉多多不多完成签到,获得积分10
27秒前
多肉丸子完成签到,获得积分10
28秒前
yian完成签到,获得积分10
28秒前
HJJHJH发布了新的文献求助30
29秒前
正直无极完成签到,获得积分10
29秒前
认真的一刀完成签到,获得积分10
29秒前
杨天天完成签到,获得积分0
29秒前
yukiseto发布了新的文献求助30
30秒前
高分求助中
【提示信息,请勿应助】关于scihub 10000
Les Mantodea de Guyane: Insecta, Polyneoptera [The Mantids of French Guiana] 3000
徐淮辽南地区新元古代叠层石及生物地层 3000
The Mother of All Tableaux: Order, Equivalence, and Geometry in the Large-scale Structure of Optimality Theory 3000
Handbook of Industrial Diamonds.Vol2 1100
Global Eyelash Assessment scale (GEA) 1000
Picture Books with Same-sex Parented Families: Unintentional Censorship 550
热门求助领域 (近24小时)
化学 材料科学 医学 生物 工程类 有机化学 生物化学 物理 内科学 纳米技术 计算机科学 化学工程 复合材料 遗传学 基因 物理化学 催化作用 冶金 细胞生物学 免疫学
热门帖子
关注 科研通微信公众号,转发送积分 4038303
求助须知:如何正确求助?哪些是违规求助? 3576013
关于积分的说明 11374210
捐赠科研通 3305780
什么是DOI,文献DOI怎么找? 1819322
邀请新用户注册赠送积分活动 892672
科研通“疑难数据库(出版商)”最低求助积分说明 815029