超级电容器
电容
材料科学
碳纤维
重量分析
氧化剂
电解质
化学工程
电化学
多孔性
碳化物衍生碳
电容感应
水溶液
碳化钛
电极
纳米技术
复合材料
碳化物
化学
计算机科学
复合数
碳纳米纤维
有机化学
物理化学
碳纳米管
工程类
操作系统
作者
Xuesha Zhang,Pengtao Yan,Ruijun Zhang,Xiaojie Xue
标识
DOI:10.1016/j.ijhydene.2016.11.171
摘要
In this paper, we present an approach to construct the compact carbon structure with high volumetric capacitive performance by means of the porous carbon structural collapse and the introduction of oxygen-containing functional groups, which is exemplarily realized by oxidizing the porous titanium carbide-derived carbon (CDC) via a modified Hummers method. Electrochemical investigations demonstrate that the oxidized CDC exhibits simultaneously outstanding volumetric capacitance (216.6 F cm−3) and high gravimetric capacitance (228 F g−1) in 6 M KOH aqueous electrolyte, almost 23 and 16 times improvement in comparison to those of the pristine CDC (9.4 F cm−3 and 14 F g−1), respectively. Furthermore, the oxidized CDC also exhibits an excellent cycling stability (almost 92% specific capacitance being retained even after 10,000 cycles). The results of this work suggests that the strategy for constructing the compact carbon structure from the porous carbon by means of the structural collapse and the introduction of oxygen-containing functional groups will be promising for the development of the electrode material with high volumetric performance for supercapacitors.
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