恶唑啉
环丙烷化
铜
重新使用
对映选择合成
催化作用
化学
组合化学
降水
有机化学
计算机科学
废物管理
物理
气象学
工程类
作者
Dorian Didier,Emmanuelle Schulz
出处
期刊:Chemcatchem
[Wiley]
日期:2011-10-12
卷期号:3 (12): 1880-1884
被引量:8
标识
DOI:10.1002/cctc.201100250
摘要
Precipitation–the solution? The recovery of a chiral copper(II) bis(oxazoline) catalyst by charge-transfer complexation and subsequent precipitation allows its efficient reuse in ene and cyclopropanation reactions for up to ten successive catalytic cycles and affords the desired products in high yields and enantioselectivities. The same catalyst batch is also successfully reused in three different asymmetric transformations in an original multireaction procedure. Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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