化学
封面(代数)
钼
钼酸盐
表征(材料科学)
配体(生物化学)
戒指(化学)
芳基
结晶学
立体化学
离子
高分子化学
纳米技术
无机化学
有机化学
材料科学
烷基
受体
工程类
机械工程
生物化学
作者
Carlos Bustos,Bernold Hasenknopf,René Thouvenot,Jacqueline Vaissermann,Anna Proust,Pierre Gouzerh
标识
DOI:10.1002/ejic.200390231
摘要
Abstract The cover picture shows a hexamolybdate anion bearing a diazenido ligand. This is a member of a promising family of functionalized polyoxomolybdates [Mo 6 O 18 (N 2 Ar)] 3− with a variety of substituents on the aryl ring. The influence of these substituents on the properties of the molybdate framework is exemplified by their different 95 Mo NMR spectra, where a special attention should be drawn to the signal of the Mo II center at very high frequencies. Details on the preparation and characterization of these and related compounds can be found in the article by P. Gouzerh et al. on p. 2757 ff.
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