Synthesis of Chiral Heterocycles Through Enantioselective Silver‐Catalyzed Transformations

Abstract This review collects the recent developments in the synthesis of chiral heterocycles through enantioselective silver‐catalyzed transformations published since 2018. It demonstrates the power of chiral silver catalysts as special mild Lewis acids to provide an impressive diversity of reaction pathways, such as 1,3‐dipolar cycloadditions, various types of cyclizations, along with a wide variety of more complex domino/tandem reactions, allowing many types of novel chiral heterocyclic products to be achieved in high enantioselectivities.