Gold Coordination‐Accelerated Multi‐Resonance TADF Emission for Efficient Solution‐Processible Ultrapure Deep‐Blue OLEDs

Abstract Multi‐resonance (MR) type emitters have emerged as highly promising candidates for high‐resolution organic light‐emitting diodes (OLEDs). However, thermally activated delayed fluorescence (TADF) emissions with simultaneous short excited state lifetimes and ultrapure blue color (a CIE y close to 0.046 and an emission peak >440 nm) have rarely been obtained for MR emitters. Herein, we report a design of dual gold‐coordinated MR molecules to achieve efficient and short‐lived ultrapure blue TADF emission. The dinuclear Au(I) complex, namely iPrAuBN , shows a narrowband deep‐blue emission with a peak maximum of 448 nm and a full width at half maximum (FWHM) of 29 nm in doped film. The coordination with two Au atoms significantly shortens the delayed fluorescence lifetime to 7.8 μs in comparison to 60.6 μs for the parental organic analogue. Solution‐processed OLED doped with iPrAuBN demonstrates an ultrapure blue electroluminescence with a peak maximum of 442 nm, a FWHM of 19 nm, CIE coordinates of (0.154, 0.036), and a maximum external quantum efficiency of 14.8 %.